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Aldrich
PEPPSI™-IPr catalyst
669032 -
98%
DOWNLOAD MSDS (PDF)Synonym: [1,3-
CAS Number: 905459-27-0
Empirical Formula (Hill Notation): C32H40Cl3N3Pd
Molecular Weight: 679.46
MDL number: MFCD08457656
PubChem Substance ID: 24884825
Properties
| Related Categories | Catalysis and Inorganic Chemistry, Homogeneous Pd Catalysts, Palladium |
| assay | 98% |
| mp | 230 °C |
Description
Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
Packaging
1, 5 g in glass btl
Application
• Catalyst for Kumada-Tamao-Corriu (KTC) reaction (eq. 1)
• Catalyst for Negishi coupling reaction (eq. 2)
• Catalyst for Suzuki coupling reaction (eq. 3)
• Catalyst for Buchwald-Hartwig amination reaction (eq. 4)
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Legal Information
PEPPSI is a trademark of Total Synthesis Ltd.
Protocols & Applications
Cross-Coupling, Amination and Heck Transformation using PEPPSI Catalysts
Price and Availability
Customers Also Purchased
Documents
Certificate of Analysis
Certificate of Origin
| Application Guide for Palladium Catalyzed Cross-Coupling (1MB) (958 KB ) |
| ChemFiles Vol 6 No 3 (1 MB ) |
| Structure Search |  |
| Similar Products |
| Ask A Scientist |
Safety Information
| Symbol |  GHS07 |
| Signal word | Warning |
| Hazard statements | H302-H312-H332 |
| Precautionary statements | P280 |
| Personal Protective Equipment | dust mask type N95 (US), Eyeshields, Gloves |
| Hazard Codes | Xn |
| Risk Statements | 20/21/22 |
| WGK Germany | 3 |
Technical information & documentation associated with this product is available in the Safety & Documentation tab.
Articles
PEPPSI™ Catalyst
Professor Mike Organ, along with Drs. Chris O’Brien and Eric Kantchev, have developed an elegant Pd-NHC catalyst system. The title complex PEPPSI stands for Pyridine-Enhanced Precatalyst Preparation ...
William Sommer
Aldrich ChemFiles 2007, 7.10, 22.
Keywords: Aminations, Buchwald-Hartwig amination, Coupling reactions, Cross couplings, Eliminations, Fischer Indole Synthesis, Ligands, Rearrangements, Reductive eliminations
PEPPSI™ Catalyst
Palladium has played a central role in the expeditious preparation of complex organic molecules, since the discovery and subsequent catalytic use of Pd(PPh3)4 by Malatesta, Angoletta and others.1 In ...
Aldrich ChemFiles 2006, 6.3, 2.
Keywords: Addition reactions, Aminations, Arylations, Building blocks, Catalysis, Chromatography, Coupling reactions, Cross couplings, Eliminations, Fischer Indole Synthesis, Flash chromatography, Grignard Reaction, Heck Reaction, Hiyama Coupling, Ligands, Natural product synthesis, Negishi Coupling, Nuclear magnetic resonance spectroscopy, Oxidative additions, Protocol, Rearrangements, Reductions, Reductive eliminations, Substitutions, Suzuki coupling, Suzuki reactions, Transmetalation
PEPPSI™-IPr
Keywords: Arylations, Drug discovery, Ligands
Accelerate your small-molecule synthesis and drug discovery success with our innovative catalyst technologies. PEPPSI™-IPr is distinguished by higher efficiency and superior functional group toleranc...
Aldrich ChemFiles 2006, 6.6, 15.
Keywords: Arylations, Drug discovery, Ligands
Related Content
PEPPSI Catalysts in Chemical Synthesis
PEPPSI™-IPr: An air- and water-stable catalysts for industrially useful intermolecular cross-coupling reactions, aminations, and intramolecular Heck transformations.
References
Organ, M. G.; Abdel-Hadi, M. et al. Chem. Eur. J. 150, 150, (2007)
Organ, M. G.; Avola, S. et al. Chem. Eur. J. 12, 4749, (2006)
Kantchev, E. A. B.; Organ, M. G. et al. Angew. Chem. Int. Ed. Engl. 46, 2768 , (2007)
Organ, M. G.; Abdel-Hadi, M. et al. Chem. Eur. J. 14, 2443, (2008)
Organ, M. G.; Avola, S. et al. Chem. Eur. J. 12, 4749, (2006)
Organ, M. G.; Abdel-Hadi, M. et al. Chem. Eur. J. 13, 150, (2007)
Kantchev, E.A.B; O'Brien, C.J.; Organ, M.G. Angew. Chem. Int. Ed. Engl. 46, 2768, (2007)
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